Controlling Volatility and Nonvolatility of Memristive Devices by Sn Alloying

Memristive devices have attracted significant attention due to their downscaling potential, low power operation, and fast switching performance. Their inherent properties make them suitable for emerging applications such as neuromorphic computing, in-memory computing, and reservoir computing. However, the different applications demand either volatile or nonvolatile operation. In this study, we demonstrate how compliance current and specific material choices can be used to control the volatility and nonvolatility of memristive devices. Especially, by mixing different materials in the active electrode, we gain additional design parameters that allow us to tune the devices for different applications. We found that alloying Ag with Sn stabilizes the nonvolatile retention regime in a reproducible manner. Additionally, our alloying approach improves the reliability, endurance, and uniformity of the devices. We attribute these advances to stabilization of the filament inside the switching medium by the inclusion of Sn in the filament structure. These advantageous properties of alloying were found by investigating a choice of six electrode materials (Ag, Cu, AgCu-1, AgCu-2, AgSn-1, AgSn-2) and three switching layers (SiO$_2$, Al$_2$O$_3$, HfO$_2$)

Atomic scale memristive photon source

Memristive devices are an emerging new type of devices operating at the scale of a few or even single atoms. They are currently used as storage elements and are investigated for performing in-memory and neuromorphic computing. Amongst these devices, Ag/amorphous-SiOx/Pt memristors are among the most studied systems, with the electrically induced filament growth and dynamics being thoroughly investigated both theoretically and experimentally. In this paper, we report the observation of a novel feature in these devices: The appearance of new photoluminescent centers in SiOx upon memristive switching, and photon emission correlated with the conductance changes. This observation might pave the way towards an intrinsically memristive atomic scale light source with applications in neural networks, optical interconnects, and quantum communication.ISSN:2047-753

Threshold Switching Enabled Sub-pW-Leakage, Hysteresis-Free Circuits

In this article, we present ultralow leakage logic circuits by combining 3-D memristors with CMOS transistors. Significant leakage current reductions of up to 99% are found by experiments and simulation for a memristive hybrid-inverter if compared with a conventional inverter. Likewise, circuit simulations of memristive hybrid ring oscillators, NAND, or full adders show more than 100% gain in energy efficiency per cycle over state-of-the-art circuits. Importantly, the memristive circuits offer hysteresis-free operation. The hysteresis-free operation is due to properly engineered properties—such as the threshold voltage—of the memristors to match the circuit, as well as the self-adaptive filament diameter of our memristor during operation. Lastly, the memristors feature a 10 8 ON– OFF ratio, enabling both high speed and low leakage (~10 fA) when integrated with a transistor. They also come with a well-controlled filament formation on a ~10-nm footprint, making them ideal to integrate with modern CMOS technology transistors.ISSN:0018-9383ISSN:1557-964

Atomic scale memristive photon source

International audienceMemristive devices are an emerging new type of devices operating at the scale of a few or even single atoms. They are currently used as storage elements and are investigated for performing in-memory and neuromorphic computing. Amongst these devices, Ag/amorphous-SiO x /Pt memristors are among the most studied systems, with the electrically induced filament growth and dynamics being thoroughly investigated both theoretically and experimentally. In this paper, we report the observation of a novel feature in these devices: The appearance of new photoluminescent centers in SiO x upon memristive switching, and photon emission correlated with the conductance changes. This observation might pave the way towards an intrinsically memristive atomic scale light source with applications in neural networks, optical interconnects, and quantum communication